General Organic Chemistry
7.0 Nomenclature of aromatic compounds
7.1 Halogen and nitro-substituted aromatics
7.2 Carboxylic acids and derivatives
7.3 Phenols and thiophenols
7.4 Aldehydes & Ketones
7.5 Sulfonic acids and sulfonic acid derivatives
7.6 Aromatic amines
7.7 Diazonium ions $\left( {ArN_2^ + } \right)$
7.0 Nomenclature of aromatic compounds
7.2 Carboxylic acids and derivatives
7.3 Phenols and thiophenols
7.4 Aldehydes & Ketones
7.5 Sulfonic acids and sulfonic acid derivatives
7.6 Aromatic amines
7.7 Diazonium ions $\left( {ArN_2^ + } \right)$
(i) General notes
The use of numbers to indicate the position of substituents on aromatic rings is supplement in the case of disubstituted derivatives of benzene by the terms,
ortho- abbreviated 0- indicating 1,2 distribution & 1,6 distribution
meta- abbreviated m- indicating 1,3 distribution & 1,5 distribution
para- abbreviated p- indicating 1,4 distribution
Examples:
benzene | |
m-iodonitrobenzene | |
o-bromochlorobenzene | |
p-chloronitrobenzene |
(ii). Aromatic hydrocarbons
The following aromatic compounds have the special name and derived group names shown below.
benzene | |
toluene | |
anisole | |
ethylbenzene | |
naphthalene | |
phenyl group (abbreviated - Ph) | |
tolyl group (o-tolyl shown) | |
anisyl group (o-anisyl shown) | |
benzyl group (abbreviated - Bz) | |
naphthyl group (2-naphthyl group) |