Carboxylic Acids and Derivatives
    10.0 Abnormal Behaviour of Formic Acid

10.0 Abnormal Behaviour of Formic Acid

The behaviour of formic acid is different from other carboxylic acid due to presence of aldehydic group.

Reaction with

1. Tollen’s reagents: formic acid behaves as a reducing agent and reduces Tollen’s reagent or Felhing solution. But others acid fail to do so.

Silver mirror

Red ppt.

2. Reaction with $HgC{l_2}$ : Formic acid forms white ppt of $H{g_2}C{l_2}$ with $HgC{l_2}$ which is converted to Grey ppt of mercury.



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