Chemistry > s Block Elements > 6.0 Alkaline Earth Metals
s Block Elements
1.0 S-Block Elements
2.0 Alkali Metals
3.0 Anamolous Behaviour of Lithium
4.0 Diagonal Relationship – similarities with magnesium
5.0 Compounds of Sodium
6.0 Alkaline Earth Metals
7.0 Diagonal Relationship – Similarities with Aluminium:
8.0 Anomalous Behaviour of Beryllium
9.0 Compounds of Calcium
6.1 Physical Properties
1. Atomic and ionic radii: Both are smaller than corresponding members of alkali metals.
2. Ionisation energy: Due to the large size of alkaline earth metals, they have fairly low values of ionization energies as compared to the p-block elements. Along the group ionization energy decreases as the atomic number increases.
Note: Because their IE is larger than that of their alkali metal neighbours, the group $2$ metals are less reactive than alkali metals. The general reactivity trend is $$Ba>Sr>Ca>Mg>Be$$
3. Electropositive or metallic character: Alkaline earth metals are highly electropositive i.e., metallic character increases down the group. However they are less electropositive than alkali metals.
4. Melting and boiling point: They have high melting and boiling points as compared to those of alkali metals due to their small size and close packing.
5. Heat of hydration: Heat of hydration of $M^{2+}$ decreases with an increase in their ionic size and their values are greater than that of alkali metal ions.
6. Reducing character: They are weaker reducing agents than alkali metals. But reducing character increases down the group because they have greater tendency to lose electrons, so they act as good reducing agents.