Chemistry > Structure of Atom > 14.0 Electronic Configuration of Elements

  Structure of Atom
    1.0 Introduction
    2.0 Cathode Ray Discharge Tube
    3.0 Thomson Model of Atom
    4.0 Rutherford Model of Atom
    5.0 Atomic Number and Mass Number and It's Relation
    6.0 Planck's Quantum Theory
    7.0 Bohr’s Atomic Model
    8.0 Dual Behaviour of Matter
    9.0 Heisenberg Uncertainity Principle
    10.0 Photoelectric Effect
    11.0 Atomic Spectra
    12.0 Quantum Mechanical Model of Atom
    13.0 Quantum Number
    14.0 Electronic Configuration of Elements

14.4 Stability of Completely Filled and Half Filled Subshells
  • The ground state electronic configuration of the atom of an element always corresponds to the state of the lowest total electronic energy.
  • in certain elements such as Cu, or Cr, where the two subshells (4s and 3d) differ slightly in their energies, an electron shifts from a subshell of lower energy (4s) to a subshell of higher energy (3d), provided such a shift results in all orbitals of the subshell of higher energy getting either completely filled or half filled.
  • It has been found that there is extra stability associated with these electronic configurations.
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