Chemistry > Thermodynamics and Thermochemistry > 1.0 Introduction to Thermodynamics

  Thermodynamics and Thermochemistry
    1.0 Introduction to Thermodynamics
    2.0 Thermodynamic Processes
    3.0 Heat $(Q)$
    4.0 Work $(W)$
    5.0 Internal Energy
    6.0 Zeroth Law of Thermodynamic
    7.0 First Law of Thermodynamics
    8.0 Heat Capacity
    9.0 Enthalpy $(H)$ or Heat Content
    10.0 Significance of $?H$ and $?E$
    11.0 Relationship Between $?H$ and $?E$
    12.0 Standard Enthalpy of Reaction
    13.0 Law of Thermodynamics
    14.0 Bond Energy or Bond Enthalpies
    15.0 Second Law of Thermodynamic
    16.0 Entropy (S)
    17.0 Spontaneous Processes
    18.0 Free Energy (G)
    19.0 Enthalpy, Entropy, Free Energy Changes and The Nature of Process
    20.0 Standard Free Energy Change
    21.0 Coupled Reactions
    22.0 Third Law of Thermodynamic
    23.0 Important Facts

1.2 Limitations of Thermodynamics
  • The laws of thermodynamics are applicable only to matter in bulk, no to individual atoms or molecules.They are not concerned with the internal structure of atoms or molecules.

  • Thermodynamics does not predict the rate at which a given process may occur. It does not tell whether the process will proceed at a faster or slower rate under the given conditions.
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