Isomerism
1.0 Isomerism
2.0 Structural Isomerism
2.1 Chain or Nuclear Isomerism
2.2 ${C_5}{H_{12}}$ stands for three chain isomers
2.3 Cyclohexane and methyl cyclopentane are nuclear isomerism
2.4 Position Isomerism
2.5 Functional Isomerism
2.6 Metamerism
2.7 Ring Chain Isomerism
3.0 Tautomerism
3.1 Structural requirement for tautomrism
3.2 Cause of tautomerism
3.3 Keto-enol tautomerim
3.4 Percentage Composition of Tautomeric Mixture
3.5 Triad System containing Nitrogen
3.6 Mechanism of tautomerism
3.7 Stereoisomerism
3.8 Geometrical Isomerism
3.9 Reason of Occurrence of geometrical Isomerism
4.0 Geometrical isomerism in the compounds containing C=N
4.1 Geometrical isomerism in the compounds containing N=N
4.2 Geometrical Isomerism in Cyclic Compounds
4.3 Stability of cis, Trans (or) Geometrical isomers
4.4 Number of Geometrical isomers
4.5 E and Z nomenclature of geometrical isomers
5.0 Optical Isomerism
5.1 Optical Activity
5.2 Asymmetric carbon (or) Chiral Carbon
5.3 Optical isomerism in bromo chloro iodo methane
6.0 Optical isomerism in compounds having more than one chiral carbons
6.1 Elements of symmetry
6.2 Centre of Symmetry
6.3 Stereoisomerism in Tartaric Acid
6.4 Calculation of number of optical isomers
7.0 Optically active compounds having no asymmetric carbon
2.4 Position Isomerism
2.2 ${C_5}{H_{12}}$ stands for three chain isomers
2.3 Cyclohexane and methyl cyclopentane are nuclear isomerism
2.4 Position Isomerism
2.5 Functional Isomerism
2.6 Metamerism
2.7 Ring Chain Isomerism
3.2 Cause of tautomerism
3.3 Keto-enol tautomerim
3.4 Percentage Composition of Tautomeric Mixture
3.5 Triad System containing Nitrogen
3.6 Mechanism of tautomerism
3.7 Stereoisomerism
3.8 Geometrical Isomerism
3.9 Reason of Occurrence of geometrical Isomerism
4.2 Geometrical Isomerism in Cyclic Compounds
4.3 Stability of cis, Trans (or) Geometrical isomers
4.4 Number of Geometrical isomers
4.5 E and Z nomenclature of geometrical isomers
5.2 Asymmetric carbon (or) Chiral Carbon
5.3 Optical isomerism in bromo chloro iodo methane
6.2 Centre of Symmetry
6.3 Stereoisomerism in Tartaric Acid
6.4 Calculation of number of optical isomers
In it, the isomers differ in the attachment of the functional group (or) substituents to the carbon chain. This is illustrated by the following examples.
(i)
(ii)
(iii)
Note: In the aromatic series, the disubstitution products of benzene also exhibit isomerism due to different relative positions occupied by the two substituents on the benzene ring.