Chemistry > Electrochemistry > 9.0 Standard Cell EMF and Standard Reduction Potential
Electrochemistry
1.0 Introduction
2.0 Conductors and Non-Conductors
3.0 Electrochemical Cells
4.0 Electrolysis and electrode Reactions
5.0 Electrochemical Cell
6.0 Electrode Potential
7.0 Nature of Electrodes
8.0 IUPAC Cell Representation and Convention
9.0 Standard Cell EMF and Standard Reduction Potential
10.0 Electropositive Character of Metals
11.0 Difference between EMF and potential difference
12.0 Nernst Equation
13.0 Laws of Electrolysis
14.0 Electromotive Force
15.0 Thermodynamics of the Cells
16.0 Concentration Cells
17.0 Battery
18.0 Fuel Cell
9.2 Applications of electrochemical series
Activity of metals depends on the tendency of losing electrons i.e., tendency of forming cation $(M^+)$, which further depends on the magnitude of standard reduction potential .
A metal is said to be chemically active if metal (having small positive value or large negative value of standard reduction potential) readily loses electrons and gets converted into cation.
Reactivity of metals decreases from top to bottom.
For example Alkali metals and alkaline earth metals have high standard reduction potential value and are chemically active. These react with cold water and evolve hydrogen. These can readily combine with acids and form corresponding salts. These combine with those which accept electron.
Metals like $Fe$, $Pb$, $Sn$, $Ni$ etc do not react with cold water but readily react with steam to evolve hydrogen.
Metals which lie below hydrogen like $Cu$, $Ag$, $Au$ etc are less reactive and do not evolve hydrogen from water.