Chemistry > p Block Elements > 8.0 Properties of Silicon

  p Block Elements
    1.0 Group $13$ – The Boron Family
    2.0 Boron
    3.0 Compounds of boron
    4.0 Compounds of Aluminium
    5.0 Group $14$ – The Carbon family
    6.0 Allotropes of Carbon
    7.0 Compounds of Carbon
    8.0 Properties of Silicon
    9.0 Group $15$-The Nitrogen Family
    10.0 Oxides of nitrogen
    11.0 Oxyacids of Nitrogen
    12.0 Phosphorus
    13.0 Oxygen
    14.0 Sulphur

8.1 Compounds of Silicon
1. Silicates:

They are the compounds in which the anions are either discrete $Si{O_4}^{4 - }$ units or a number of such units combine together as shown in the figure.

$Si{O_4}^{4 - }$ tetrahedron is shown in which small open circles represent oxygen atoms and centre dot represents the silicon atom.

Silicates are classified on the basis of number of corners of $Si{O_4}^{4 - }$ tetrahedron shared with other units as follows:

  • Orthosilicates: They do not share ant corner.


  • Pyrosilicate: Two tetrahedra share one corner to form $S{i_2}{O_7}^{6 - }$ anion.


  • Cyclic or ring silicates: Two corners of each tetrahedron are shared to form closed rings.


  • Chain silicates, sheet silicates and three dimensional silicates.
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