Chemistry > p Block Elements > 5.0 Group $14$ – The Carbon family

  p Block Elements
    1.0 Group $13$ – The Boron Family
    2.0 Boron
    3.0 Compounds of boron
    4.0 Compounds of Aluminium
    5.0 Group $14$ – The Carbon family
    6.0 Allotropes of Carbon
    7.0 Compounds of Carbon
    8.0 Properties of Silicon
    9.0 Group $15$-The Nitrogen Family
    10.0 Oxides of nitrogen
    11.0 Oxyacids of Nitrogen
    12.0 Phosphorus
    13.0 Oxygen
    14.0 Sulphur

5.1 Physical Properties
Covalent Radii: There is an increase in covalent radii from $C$ to $Si$, thereafter from $Si$ to $Pb$ a small increase in radius due to the presence of completely filled $d$ and $f$ orbitals in heavier members.


Ionisation Energies: The higher ionization energies than group $13$ is due to the higher nuclear charge and smaller size of atoms of group $14$ elements. While moving down the group, the ionisation energies decreases till $Sn$. From $Sn$ to $Pb$ as a consequence of poor shielding effect of intervening $d$ and $f$ orbitals and increase in size of the atom, ionisation energy increases. $$C>Si>Ge>Sn<Pb$$


Catenation: It is the ability of the atoms to link with one another through covalent bonds. Its tendency decreases from $C$ to $Pb$ due to the decreasing $M-M$ single bond energy.



Allotropy: Except lead all other elements exhibit allotropy. Allotropic forms are:

$C$: crystalline and microcrystalline
$Si$: crystalline and amorphous
$Ge$: $2$ crystalline forms
$Sn$: $3$ solid forms (grey tin, white tin and rhombic tin)

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