Chemistry > p Block Elements > 5.0 Group $14$ – The Carbon family
p Block Elements
1.0 Group $13$ – The Boron Family
2.0 Boron
3.0 Compounds of boron
4.0 Compounds of Aluminium
5.0 Group $14$ – The Carbon family
6.0 Allotropes of Carbon
7.0 Compounds of Carbon
8.0 Properties of Silicon
9.0 Group $15$-The Nitrogen Family
10.0 Oxides of nitrogen
10.1 Nitrogen Oxide $N_2O$ or Laughing gas (Neutral)
10.2 Nitric Oxide $NO$ (Neutral)
10.3 Nitrogen trioxide $N_2O_3$
10.4 Nitrogen dioxide or Di-nitrogen tetroxide $NO_2$ or $N_2O$
10.5 Nitrogen pentaoxide $N_2O_5$
11.0 Oxyacids of Nitrogen
11.1 Nitric acid $HNO_3$
11.2 Oxidation of Metalloid and Inorganic compounds by Nitric acid
11.3 Action of Metals & Proteins
12.0 Phosphorus
13.0 Oxygen
14.0 Sulphur
5.1 Physical Properties
10.2 Nitric Oxide $NO$ (Neutral)
10.3 Nitrogen trioxide $N_2O_3$
10.4 Nitrogen dioxide or Di-nitrogen tetroxide $NO_2$ or $N_2O$
10.5 Nitrogen pentaoxide $N_2O_5$
11.2 Oxidation of Metalloid and Inorganic compounds by Nitric acid
11.3 Action of Metals & Proteins
Covalent Radii: There is an increase in covalent radii from $C$ to $Si$, thereafter from $Si$ to $Pb$ a small increase in radius due to the presence of completely filled $d$ and $f$ orbitals in heavier members.
Ionisation Energies: The higher ionization energies than group $13$ is due to the higher nuclear charge and smaller size of atoms of group $14$ elements. While moving down the group, the ionisation energies decreases till $Sn$. From $Sn$ to $Pb$ as a consequence of poor shielding effect of intervening $d$ and $f$ orbitals and increase in size of the atom, ionisation energy increases. $$C>Si>Ge>Sn<Pb$$
Catenation: It is the ability of the atoms to link with one another through covalent bonds. Its tendency decreases from $C$ to $Pb$ due to the decreasing $M-M$ single bond energy.
Allotropy: Except lead all other elements exhibit allotropy. Allotropic forms are:
$C$: crystalline and microcrystalline
$Si$: crystalline and amorphous
$Ge$: $2$ crystalline forms
$Sn$: $3$ solid forms (grey tin, white tin and rhombic tin)