Chemistry > Surface Chemistry > 2.0 Adsorption

  Surface Chemistry
    1.0 Introduction
    2.0 Adsorption
    3.0 Factors affecting adsorption of gases by solids
    4.0 Adsorption Isotherms
    5.0 Applications of Adsorption
    6.0 Types of Solutions
    7.0 Colloidal System
    8.0 Coagulation of colloidal solutions
    9.0 Emulsions
    10.0 Catalysis
    11.0 Zeolites as shape-selective catalysts
    12.0 Enzyme as catalysts

2.1 Characteristics of Adsorption
1. It is specific and selective in nature.

2. It is accompanied by decrease in the free energy of the system. When $\Delta G$ becomes zero, adsorption equilibrium is established.

3. Adsorption is a spontaneous process therefore change in free energy $\left( {\Delta G} \right)$ for the process is negative.

According to Gibbs-Helmholtz equation, $$\Delta G = \Delta H - T\Delta S$$$$\Delta G = - ve;\;\Delta H = - ve$$
Since, it is a exothermic process. $\Delta S$ is negative because adhering of gas molecules to the surface lowers the randomness.
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