Chemistry > Surface Chemistry > 2.0 Adsorption
Surface Chemistry
1.0 Introduction
2.0 Adsorption
3.0 Factors affecting adsorption of gases by solids
4.0 Adsorption Isotherms
5.0 Applications of Adsorption
6.0 Types of Solutions
7.0 Colloidal System
7.1 Different Colloidal Systems
7.2 Classification of Colloidal System
7.3 Preparation of Colloidal System
7.4 Purification of Colloidal System
7.5 Properties of colloidal system
8.0 Coagulation of colloidal solutions
9.0 Emulsions
10.0 Catalysis
11.0 Zeolites as shape-selective catalysts
12.0 Enzyme as catalysts
12.1 Characteristics of Enzymes
12.2 Mechanism of enzyme catalysis
12.3 Autocatalysis
12.4 Induced catalysis
2.1 Characteristics of Adsorption
7.2 Classification of Colloidal System
7.3 Preparation of Colloidal System
7.4 Purification of Colloidal System
7.5 Properties of colloidal system
12.2 Mechanism of enzyme catalysis
12.3 Autocatalysis
12.4 Induced catalysis
1. It is specific and selective in nature.
2. It is accompanied by decrease in the free energy of the system. When $\Delta G$ becomes zero, adsorption equilibrium is established.
3. Adsorption is a spontaneous process therefore change in free energy $\left( {\Delta G} \right)$ for the process is negative.
According to Gibbs-Helmholtz equation, $$\Delta G = \Delta H - T\Delta S$$$$\Delta G = - ve;\;\Delta H = - ve$$
Since, it is a exothermic process. $\Delta S$ is negative because adhering of gas molecules to the surface lowers the randomness.