Chemistry > Surface Chemistry > 7.0 Colloidal System

  Surface Chemistry
    1.0 Introduction
    2.0 Adsorption
    3.0 Factors affecting adsorption of gases by solids
    4.0 Adsorption Isotherms
    5.0 Applications of Adsorption
    6.0 Types of Solutions
    7.0 Colloidal System
    8.0 Coagulation of colloidal solutions
    9.0 Emulsions
    10.0 Catalysis
    11.0 Zeolites as shape-selective catalysts
    12.0 Enzyme as catalysts

7.4 Purification of Colloidal System
1. Dialysis
Dialysis may be defined as the process of separating a crystalloid from a colloid by diffusion or filtration through a fine membrane, the membrane (or apparatus) used for the purpose is known as dialyser.

The process of dialysis can be quickened by using hot water (hot dialysis) or by applying an electric field (electrodialysis).



2. Ultrafilitration
Sol particles directly pass through ordinary filter paper because their pores are larger than size of sol particles. But if the pores of the ordinary filter paper are made smaller by soaking the filter paper in a solution of gelatin or colloidion and subsequently hardened by soaking in formaldehyde, the treated filter paper may retain colloidal particles and allow the true solution particles to escape.

Such filter is known as ultrafilter and the process of separating colloids by using ultrafilters is known as ultrafilitration.



3. Ultracentrifugations
The sol particles are prevented from settling out under the action of gravity by kinetic imparts of the molecules of the medium. However, the setting force can be enhanced by using high speed centrifugal machines having $15,000$ or more revolutions per minute.

Such machines are known as ultracentrifuges.
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