Chemistry > Practical Organic Chemistry > 3.0 Detection of Functional Group

  Practical Organic Chemistry
    1.0 Detection of Elements in Organic Compound
    2.0 Summary of Solubilitiy Behaviour
    3.0 Detection of Functional Group
    4.0 Methods of Separation of Mono-functional Organic Compounds from Binary Mixtures
    5.0 Separation based on Differences in the volatilities of the component in aqueous solution
    6.0 Determination of Empirical Formula and Molecular Formula
    7.0 Solved Example (Subjective)

3.1 Test for Alcoholic Hydroxyl Group
1. Sodium Test: to 1 mL of aqueous (or alcoholic) solution of the compound add a few drops of ferric chloride solution. A violet, red, blue or green colouration indicates the presence of a phenolic group.

2. Ceric Ammonium Nitrate: to 1 mL of an aqueous hot solution of the compound, add a few drops of ceric ammonium nitrate. A green or brown precipitate indicates the presence of $–OH$ group.

3. Molybdate Test: Heat a little of the organic compound with 2 pellets of $KOH.$ Cool and add 1 mL of ether and 2-3 drops of $C{S_2}$. A yellow or precipitate will be obtained. Filter the solution and to the filtrate add 1 mL of ammonium molybdate solution and excess of dilute $HCl.$ A red or blue colouration indicates the presence of $–OH$ group.
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