Chemistry > Practical Organic Chemistry > 2.0 Summary of Solubilitiy Behaviour

  Practical Organic Chemistry
    1.0 Detection of Elements in Organic Compound
    2.0 Summary of Solubilitiy Behaviour
    3.0 Detection of Functional Group
    4.0 Methods of Separation of Mono-functional Organic Compounds from Binary Mixtures
    5.0 Separation based on Differences in the volatilities of the component in aqueous solution
    6.0 Determination of Empirical Formula and Molecular Formula
    7.0 Solved Example (Subjective)

2.5 Water-insoluble hydrocarbons and oxygen compounds that do not contain N or S and are soluble in cold concentrated sulphuric acid
Any changes – colour, excessive charring, the evolution of gases or heat, polymerization and precipitation of an insoluble compound – attending the dissolution of the substance should be carefully noted.
Alcohols, esters (but not ethyl benzoate, diethyl malonate or diethyl oxalate), aldehydes, methyl ketones and cyclic ketones containing less than nine carbon atoms as well as ethers containing less than seven carbon atoms are also soluble in 85 percent phosphoric acid.

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