Chemistry > Carboxylic Acids and Derivatives > 6.0 Reaction Involving Cleavage of —OH Group

  Carboxylic Acids and Derivatives
    1.0 Nomenclature
    2.0 General Methods of Preparation
    3.0 Physical Properties of Carboxylic Acid
    4.0 Chemical Properties of Carboxylic Acid
    5.0 Ortho Effect
    6.0 Reaction Involving Cleavage of —OH Group
    7.0 Reaction Involving —COOH Group
    8.0 Hell-Volhard-Zelinsky Reaction
    9.0 Heating of Dicarboxylic Acids
    10.0 Abnormal Behaviour of Formic Acid
    11.0 Derivatives of Carboxylic Acid
    12.0 Relative Reactivity of Acid Derivatives
    13.0 Resonance Effect
    14.0 Acyl Chloride RCOCl
    15.0 Amides
    16.0 Ester (RCOOR)
    17.0 Acid Anhydrides
    18.0 Method of Preparation

6.1 Esterification

When carboxylic acid reacts with alcohol in the presence of conc. ${H_2}S{O_4}$ to form ester, which is known as esterification

The relative reactivity of alcohol to ester formation markedly dependent on their structure. The greater the bulk of the substituents near the $—OH$ group, the slower the reaction would be same facts is followed by acid as well


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