Chemistry > Carboxylic Acids and Derivatives > 6.0 Reaction Involving Cleavage of —OH Group
Carboxylic Acids and Derivatives
1.0 Nomenclature
2.0 General Methods of Preparation
3.0 Physical Properties of Carboxylic Acid
4.0 Chemical Properties of Carboxylic Acid
5.0 Ortho Effect
6.0 Reaction Involving Cleavage of —OH Group
6.1 Esterification
6.2 Formation of acid chloride
6.3 Formation of Acid Anhydride
6.4 Formation of Amides
7.0 Reaction Involving —COOH Group
8.0 Hell-Volhard-Zelinsky Reaction
9.0 Heating of Dicarboxylic Acids
10.0 Abnormal Behaviour of Formic Acid
11.0 Derivatives of Carboxylic Acid
12.0 Relative Reactivity of Acid Derivatives
13.0 Resonance Effect
14.0 Acyl Chloride RCOCl
15.0 Amides
16.0 Ester (RCOOR)
17.0 Acid Anhydrides
18.0 Method of Preparation
18.1 Acylation
18.2 Sodium salt of carboxylic acids also react with acyl chlorides to give
18.3 Cyclic anhydrides
18.4 Chemical Properties
6.1 Esterification
6.2 Formation of acid chloride
6.3 Formation of Acid Anhydride
6.4 Formation of Amides
18.2 Sodium salt of carboxylic acids also react with acyl chlorides to give
18.3 Cyclic anhydrides
18.4 Chemical Properties
When carboxylic acid reacts with alcohol in the presence of conc. ${H_2}S{O_4}$ to form ester, which is known as esterification
The relative reactivity of alcohol to ester formation markedly dependent on their structure. The greater the bulk of the substituents near the $—OH$ group, the slower the reaction would be same facts is followed by acid as well