Chemistry > d and f Block Elements > 5.0 Potassium permanganate

  d and f Block Elements
    1.0 General Introduction and Electronic Configuration
    2.0 Occurrence and General Characteristics of Transition Elements
    3.0 General Trends in properties of First Row Elements
    4.0 Potassium dichromate
    5.0 Potassium permanganate
    6.0 F-Block Elements - Introduction
    7.0 Lanthanoid Series
    8.0 Lanthanoid Contraction and its consequence
    9.0 Actinoids Series
    10.0 Comparison between lanthanoids and actinoids

5.2 Structure of manganate ion and permanganate ion
  • $Mn$ atom in $Mn{O_4}^{ - }$ is $s{p^3}$ hybridized.

  • $Mn-O$ $\pi $ bonds are formed by overlaping of $p$-orbital of oxygen and $d$-orbitals of $Mn$.

  • Both manganate and permanganate ions are tetrahedral.

  • Their geometry is tetrahedral.

  • Manganates are green in colour and paramagnetic have one unpaired electron.

  • Permanganate ions are purple in colour and diamagnetic.
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